These Celeb Relationships Began As Affairs

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Brad Pitt and Angelina Jolie
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NBC News

Jennifer Aniston had been in Heidi Bivens shoes many years before. Her first husband was Brad Pitt, whom she married in 2000 but divorced in 2005. The reason? He did Mr. & Mrs. Smith, or more bluntly, he DID Mrs. Smith. Angelina Jolie was the apple of his eye, and he would leave the lovely Aniston for her.

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